Stress corrosion cracking international institute of. Pdf stress corrosion cracking behaviour of dissimilar welding of. The applications for stainless steels in petroleum refining are many and varied. Stress corrosion cracking susceptibility of 304l substrate.
However, when it is subjected to crevice corrosion andor pitting in warm chloride conditions and stress corrosion cracking 316316l stainless steel can breakdown and experience premature failure. The effect of cold work on the stresscorrosion cracking. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Stress corrosion cracking behavior of nickel base alloys. Surface finishing treatments such as shot blasting and wire brushing can be beneficial in improving the integrity of machined surfaces of austenitic stainless steels. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Effects of marine environments on stress corrosion. The chief applications of hastelloy alloys are in the presence of hot chloride solutions. We inventory 304, 209, 310, 316 and 321 stainless steel pipe, bar. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Outside diameter stress corrosion cracking of stainless steel. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Type ss 316 is the next most common austenitic stainless steel. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Austenitic stainless steel 304, 309, 310, 316 and 321 great plains. Influence of high temperature on corrosion behavior of 304. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. In these media, many stainless steel grades suffer from crevice corrosion, pitting corrosion and stress corrosion cracking. The purpose of this booklet, therefore, is to help materials engineers identify those applications and to provide data to support the use of stainless steels in the hightemperature, corrosive environments that may be encountered. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Effects of fluoride and other halogen ions on the external. The lower nickel content of cs309 improves resistance to sulphur attack at high temperatures.
When frequent thermal cycling is involved, the alloy is resistant to about 1850f. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Type 304 is the most widely used alloy of all stainless steels. The effect of cold work on the stresscorrosion cracking of. Caustic stress corrosion cracking inspectioneering.
Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. This material was initially developed for use in paper mills, yet is frequently used in. Why are austenitic stainless steels more susceptible to chloride stress corrosion cracking than ferritic stainless steels. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Effect of nitrogen on the microstructure and stress corrosion. Jan 12, 2020 grade 309 is a high temperature chromium nickel austenitic stainless steel that resists oxidation at temperatures up to 1900. Both of type 304 and type 316 stainless steels showed quite similar. Chloride induced stress corrosion cracking of type 304 and. Microstructure and stress corrosion cracking of a sa508. Stress corrosion behavior of stainless steel welds in high temperature water containing chlorides in tests with three different grades of aisi 308, 309 and 316 stainless steels, a type 376.
A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3,4,5. Effect of weld metal chemistry on stress corrosion cracking behavior. Scc in a 316 stainless steel chemical processing piping system. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Stress corrosion behavior of stainless steel welds in high. A 7 year old furnace made out of 309l stainless steel developed cracks in a particular region of the vessel. Stress corrosion cracking industrial metallurgists. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. They are magnetic, have good ductility and resistance to corrosion and oxidation.
Some observations of stress corrosion cracking in austenitic. Ss 316 austenitic stainless steel grade steelindo persada. Deterioration by clscc can lead to failures that have the potential to release. Stress corrosion cracking in a brewery paul mueller company. One of the primary characteristics of austenitic stainless steel is its corrosion resistance. Dust and aerosols in the air being drawn though ventilation openings in the concrete overpack may be deposited on the stainless steel canister outer surfaces. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc results from the combined action of stress, a cracking electrochemical environment, and temperature to cause cracks to initiate and grow in susceptible steel. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Corrosionpedia what is stress corrosion cracking scc. Stress corrosion cracking of sensitized type 304 stainless.
Type 430 is the generalpurpose stainless of the ferritic group. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions aip advances 6, 115301 2016. Alloy 309309s heat resistnat stainless steel plate. Stress corrosion cracking behaviour of dissimilar welding. Stress corrosion cracking resistance of super 304h stainless steel was deteriorated by gta welding due to the formation of susceptible microstructure in the haz. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Intergranular stress corrosion cracking of welded steel twi. Lean duple stainless steel product description ak steel nitronic 19d stainless steel is a lean duplex stainless steel with a mixed ferrite and austenite structure. Scc is the main corrosion failure mode for 310s stainless steels and. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Under thermal cycling conditions this grade resists oxidation up to a temperature of. In this study, ground steel surfaces were subjected to a series of sand blasting and wire brushing. Pitting and stress corrosion cracking scc studies on the 316n stainless steel ss weldments in aswelded aw and thermally aged solution annealing sa, 550 c4 h and 750 c1 h conditions were carried out in acidic and acidic chloride media. Effect of nitrogen on the microstructure and stress corrosion cracking of stainless steel weld metals nitrogen pickup from the atmosphere during welding can cause elimination of delta ferrite and an increase in the susceptibility to stress corrosion cracking by w.
Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Stress corrosion cracking scc is a common issue with many specialty alloys. Chloride stress corrosion cracking resistance, lower coefficient of thermal. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The most common austenitic stainless steel and most common of all stainless steel is type ss 304, also known as 188 or a2. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Feb 15, 2017 aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. This paper will present some history of this corrosion concern in nuclear reactors and discuss the environmental conditions where outside diameter stress corrosion cracking odscc of stainless.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. This alloy provides high yield strength, good drawing and welding characteristics, excellent chloride stress corrosion cracking resistance, and high cyclic oxidation resistance. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The susceptibility to stress corrosion cracking as judged by the. These operations optimize inservice properties such as resistance to pitting corrosion and stress corrosion cracking scc. A laboratory test using a solution of magnesium chloride boiling at 309 f. Individual cracks are generally oriented perpendicular to the maximum stress and parallel to the tube pipe axis. Hastelloy c276 has minor corrosion rates in reducing and oxidizing conditions. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
The high chromium and relatively low nickel content of 309 provide good resistance to high temperature sulfur bearing atmospheres. In tests with three different grades of aisi 308, 309 and 316 stainless steels, a. Pitting and stress corrosion cracking studies on aisi type. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. The interaction of corrosion fatigue and stresscorrosion. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Fz of 309, 309mo, and 309cb sss, relative to that of 316 ss, considerably reduce the scc resistance in a. Why are austenitic stainless steels more susceptible to.
Pitting and stress corrosion cracking studies on aisi type 316n stainless steel weldments. Detecting and imaging stress corrosion cracking in. A locking ring made of ferritic stainless steel, fitted in a pressure. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Issf martensitic stainless steels 10 oil and gas recovery. New grades most of them proprietary more resistant to stress corrosion cracking scc and sulfide stress cracking ssc are now under development and are. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
This mode of attack is termed stress corrosion cracking scc. This paper presents a fusion welding process that was developed for snf canister repair. Its high chromium and nickel content provides comparable corrosion resistance, superior resistance to oxidation, and the retention of a larger fraction of room temperature strength than the common austenitic alloy 304. Microstructure and stress corrosion cracking of a sa508309l. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Stress corrosion cracking scc of duplex stainless steel. Recent research on las 309 l308 l stainless steel weld joint revealed stress corrosion crack growth occurred in the haz of 316 l stainless steel in offnormal water chemistry of primary pwr environment with do, whereas the 308 l weld metal showed a high resistance to stress corrosion crack growth 9,10. In short, you cant have cscc if one element is missing. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system.
Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Chloride stress corrosion cracking cscc requires chloride and stress. Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride deposits, corrosion 65, 105. Chloride stress corrosion cracking in austenitic stainless steel. Jun 06, 2019 300 series stainless steels are the larger subgroup. Known for its corrosion resistance and wide range of uses in food handling, cutlery, and many other applications, stainless steel is one of the most popular metals in use today. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Sensor requirements for detection and characterization of. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Cs 309 is a highly alloyed austenitic stainless steel used for its excellent oxidation resistance, high temperature strength and creep resistance. Stress corrosion cracking is the cracking of a susceptible metal under the mixed.
Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. Pitting and stress corrosion cracking studies on aisi type 316n. Stainless steels are more resistant to general corrosion compared with carbon steel. In regions of high residual weld stresses, this may lead to localized stress corrosion cracking scc. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The dozens of alloy variants make welding stainless steel more complicated than welding traditional carbon steel. This is somewhat surprising because the highest mechanical properties obtainable from these three semiaustenitic stainless steels are produced by condition ch900.